HA(aq) + OH- --> A-(aq) + H2O(L)
if weak acid is in excess --> a buffer --> Hendeson Hasselbalch equaiton
if strong base is in excess, the moles of excess hydroxide ions is used for pH
if acid and base are equimolar then the equilibrium concentr
Frozen!
Frozen!
Boost!
Boost!
strong acid strong base equivalence pointpH = 7 @ 25 C / 298 K
how to increase/decrease buffering capacity
equivalence point
H2O pH is always...7, could be acid (pH) or base (pOH)
1.0 x 10^-14 at 25 C or 298 K
14 always!!
how do you calculate a buffer's pHpH = pKa + log [A-]/[HA] ---> acids
pOH = pKb + log [BH+]/[B] ---> bases
the conjugate salt is on top, and the bottom is either the base or the acid
assume there is a limiting and excess reagent (because it will contain either a strong acid or base)
pH = pKa
strong acid-weak base reactionif weak base is in excess --> a buffer --> Hendeson Hasselbalch equaiton
if strong acid is in excess, the moles of excess acid are used to determine pH
if acid and base are equimolar then the equilibrium concentrations are used to determine pH
what is a buffer
in what range are buffers effectivewithin 1 pH of its pKa, up or down
H2O pH is always...
Frozen!
Frozen!
maximum buffering capacity
Kw =1.0 x 10^-14 at 25 C or 298 K
what is a buffer
how to increase/decrease buffering capacityincreasing/decreasing concentrations of buffer components, but keeping the ratios constant (if you don't it'll change the buffer capacity for either acid or base respectively)
pH + pOH =14 always!!
how do you calculate a buffer's pH
equivalence point
Boost!
Boost!
pH = 7 @ 25 C / 298 K
in what range are buffers effectivewithin 1 pH of its pKa, up or down
weak acid-strong base reactionHA(aq) + OH- --> A-(aq) + H2O(L)
if weak acid is in excess --> a buffer --> Hendeson Hasselbalch equaiton
if strong base is in excess, the moles of excess hydroxide ions is used for pH
if acid and base are equimolar then the equilibrium concentr
if weak base is in excess --> a buffer --> Hendeson Hasselbalch equaiton
if strong acid is in excess, the moles of excess acid are used to determine pH
if acid and base are equimolar then the equilibrium concentrations are used to determine pH