HA(aq) + OH- --> A-(aq) + H2O(L) if weak acid is in excess --> a buffer --> Hendeson Hasselbalch equaiton if strong base is in excess, the moles of excess hydroxide ions is used for pH if acid and base are equimolar then the equilibrium concentr
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strong acid strong base equivalence point pH = 7 @ 25 C / 298 K
how to increase/decrease buffering capacity
equivalence point
H2O pH is always... 7, could be acid (pH) or base (pOH)
1.0 x 10^-14 at 25 C or 298 K
14 always!!
how do you calculate a buffer's pH pH = pKa + log [A-]/[HA] ---> acids pOH = pKb + log [BH+]/[B] ---> bases the conjugate salt is on top, and the bottom is either the base or the acid assume there is a limiting and excess reagent (because it will contain either a strong acid or base)
pH = pKa
strong acid-weak base reaction if weak base is in excess --> a buffer --> Hendeson Hasselbalch equaiton if strong acid is in excess, the moles of excess acid are used to determine pH if acid and base are equimolar then the equilibrium concentrations are used to determine pH
what is a buffer
in what range are buffers effective within 1 pH of its pKa, up or down
H2O pH is always...
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maximum buffering capacity
Kw = 1.0 x 10^-14 at 25 C or 298 K
what is a buffer
how to increase/decrease buffering capacity increasing/decreasing concentrations of buffer components, but keeping the ratios constant (if you don't it'll change the buffer capacity for either acid or base respectively)
pH + pOH = 14 always!!
how do you calculate a buffer's pH
equivalence point
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pH = 7 @ 25 C / 298 K
in what range are buffers effective within 1 pH of its pKa, up or down
weak acid-strong base reaction HA(aq) + OH- --> A-(aq) + H2O(L) if weak acid is in excess --> a buffer --> Hendeson Hasselbalch equaiton if strong base is in excess, the moles of excess hydroxide ions is used for pH if acid and base are equimolar then the equilibrium concentr
if weak base is in excess --> a buffer --> Hendeson Hasselbalch equaiton if strong acid is in excess, the moles of excess acid are used to determine pH if acid and base are equimolar then the equilibrium concentrations are used to determine pH
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